In order to continue enjoying our site, we ask that you confirm your identity as a human. Thank you very much for your cooperation. Show A solution is a homogeneous mixture of two or more pure substances on molecular level whose composition can vary within certain limits. A solution has two components (substances) known as solute and the solvent. A supersaturated solution contains more dissolved solute than required for preparing a saturated solution and can be prepared by heating a saturated solution, adding more solute, and then cooling it gently. Excess dissolved solute crystallizes by seeding supersaturated solution with a few crystals of the solute. For example, the object of pan boiling is the production of a fine even crop of sugar crystals. A primary condition for the attainment of this end is the maintenance of a control over the rate of crystallization during the growth. Basically, a crystal surface maintained in a solution will only grow if the concentration of the solution is maintained at a level greater than the saturation concentration. Such a solution is said to be supersaturated. Supersaturation in Phase Change (Crystallization and Condensation)
Applications of Supersaturated SolutionWhen a solution of a solid solute dissolved in a liquid solvent is saturated, it is in thermodynamic equilibrium. In order for crystallization to occur, the state of the system must be shifted to a nonequilibrium state in which the concentration of the solute in the solution exceeds its equilibrium concentration at the given solution conditions. Solutions that are in the nonequilibrium state are said to be supersaturated. The simplest method to create a supersaturated solution is by cooling. A solution is initially prepared at point A. If this solution is cooled it will be saturated when it intersects the saturation line. If it is cooled past the saturation line to point B it will be supersaturated. Just because this solution is supersaturated, however, does not mean that it will immediately crystallize. Supersaturated solutions are metastable. This means that there is a free energy barrier which must be overcome for the phase transition to be overcome. The simplest and most common method of making a supersaturated solution is by cooling, but this is not the only method that can be used, there are many methods like solvent evaporation, temperature change, change in pH, chemical reaction and alteration in solvent composition. Examples of Supersaturated SolutionSupersaturated solution contains more dissolved substances than a saturated solution. For example, 40g NaCl in 100ml H2O. The additional 4.0g NaCl remains undissolved. Solved Examples1. What is the mass percent of sodium hydroxide in a solution that is made by dissolving 8.00g NaOH in 50.0g H2O? Solution: Knowns 8.00g NaOH 50.0g H2O Solving for mass percent = 8.00g NaOH/8.00g NaOH + 50.0g H2O = 13.8% NaOH solution. 2. Will a solution made by adding 2.5g of CuSO4 to 10g of H2O be saturated for unsaturated at 20oC? Solution: We first need to know the solution of CuSO4 at 20oC. From figure 14.4 we see that the solubility of CuSO4 at 20oC is about 21g per 100g of H2O. This amount is equivalent to 2.1g of CuSO4 per 10g of H2O. Since 2.5g per 10g of H2O is greater than 2.1g per 10g of H2O, the solution will be saturated and 0.4g of CuSO4 will be maintained.
A supersaturated solution is a more solute solution than can be dissolved by the solvent. If you haven’t learned what a solute / solvent is, the material that is dissolved in the solution, such as salts but not restricted to salts, is a solution. The most popular example is sodium acetate which is supersaturated.
A supersaturated solution is a solution that contains more than the average solvent that can be dissolved at a given temperature. The recrystallization of the excess dissolved solvent in a super-saturated solution can be started by inserting a tiny solute crystal, called a seed crystal.
According to the solubility of the substance a “supersaturated” solution produces more dissolved content than it should. In the case of sugar, whose chemical name is “sucrose,” approximately 211 grams of water can dissolve in 100 millilitres. Solubility is temperature dependent; more sugar dissolves in hot water than in cold.
Under appropriate conditions, solutions may often be formulated that contain a greater amount of solvent than the one required to form a saturated solution. Owing to the presence of the solute in a supersaturated solution in a concentration greater than the concentration of equilibrium, super-saturated solutions are unstable.
The solid crystals in the hydrated crystals will dissolve into the bath, forming a supersaturated solution. When the solution for sodium thiosulfate is gradually cooled the super-saturated solution should remain liquid. Placing a small crystal in the over-saturated solution would make the liquid solid.
Put your understanding of this concept to test by answering a few MCQs. Click ‘Start Quiz’ to begin! Select the correct answer and click on the “Finish” button
Visit BYJU’S for all Chemistry related queries and study materials
0 arewrong out of 0 are correct out of0 are Unattempted out of
A saturated solution is a chemical solution containing the maximum concentration of a solute dissolved in the solvent. The additional solute will not dissolve in a saturated solution. The amount of solute that can be dissolved in a solvent to form a saturated solution depends on a variety of factors. The most important factors are:
You encounter saturated solutions in daily life, not just in a chemistry lab. Also, the solvent does not need to be water. Here are some common examples:
If one substance will not dissolve into another, you cannot form a saturated solution. For example, when you mix salt and pepper, neither dissolves in the other. All you get is a mixture. Mixing oil and water together will not form a saturated solution because one liquid does not dissolve in the other. There's more than one way to make a saturated solution. You can prepare it from scratch, saturate an unsaturated solution, or force a supersaturated solution to lose some solute.
The definition of a supersaturated solution is one which contains more dissolved solute than could ordinarily dissolve into the solvent. A minor disturbance of the solution or introduction of a "seed" or tiny crystal of solute will force crystallization of excess solute. One way supersaturation can occur is by carefully cooling a saturated solution. If there is no nucleation point for crystal formation, the excess solute may remain in solution. |